Exploitation of reversed micelles as membrane mimetic reagents |
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Authors: | Charmian J OConnor Terenece D Lomax Robyn E Ramage |
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Institution: | Chemistry Department, University of Auckland, Private Bag, Auckland, New Zealand. |
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Abstract: | The aqueous micelle model and its relation to the various models proposed for aggregation of surfactants in nonaqueous solvents, and the controversy surrounding the applicability of the critical micelle concentration to these aggregates, have been discussed. The effect of the addition of water to, and the nature of acid-base interactions in, surfactants solutions in apolar solvents have been included in a review of the kinetics of the reactivity of esters and other organic sustrates, inoragatic reaction mechanisms, catalysis by solubilized enzymes and electron and proton transfer reactions in these media. Where possible, analogies have been made with membrance mediated processes. |
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