| 铜配合物在Y型分子筛超笼中的组装及其催化苯酚羟化活性 |
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| 引用本文： | 齐兴义,郭林,吴越.铜配合物在Y型分子筛超笼中的组装及其催化苯酚羟化活性[J].催化学报,2002,23(2):101-102. |
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| 作者姓名： | 齐兴义 郭林 吴越 |
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| 作者单位： | Faculty of Materials Science and Engineering, Beijing University of Aeronautics and Astronautics, Beijing 100083, China,Changchun Institute of Applied Chemistry, The Chinese Academy of Sciences, Changchun 130022, Jilin, China |
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| 摘 要： | 详尽介绍了通过分步法，在Y型分子筛超笼中制备铜（II）- 1，10菲咯啉和8-羟基喹啉配合物（简称CuPhen/Y，CuOx/Y）的过程；活性评价结果显示同Cu/Y相比，以H2O2为氧化剂，CuPhen/Y，CuOx/Y具有特殊的催化苯酚羟化功能。
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| 关 键 词： | 铜(II)配合物 菲咯啉 8-羟基喹啉 Y分子筛 苯酚 羟化 |
| 文章编号： | 0253-9837(2002)02-0101-02 |
| 收稿时间： | 2002-04-25 |
| 修稿时间： | 2001年10月29日 |
Assembly of Cu(Ⅱ)-1,10-Phenanthroline and Oxine Complexes in Supercages of Y Zeolite and Their Catalytic Activity for Phenol Hydroxylation |
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| QI Xingyi,GUO Lin,WU Yue.Assembly of Cu(Ⅱ)-1,10-Phenanthroline and Oxine Complexes in Supercages of Y Zeolite and Their Catalytic Activity for Phenol Hydroxylation[J].Chinese Journal of Catalysis,2002,23(2):101-102. |
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| Authors: | QI Xingyi GUO Lin WU Yue |
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| Abstract: | In biological systems, monooxygenase, exemplified by cytochrome P-450, can efficiently catalyze hydroxylation and epoxidation of organic substrates by molecular oxygen as the terminal oxidant. For this reason, a lot of attention has been paid to the continuous research to explore chemical models in order to provide a basis for deeper understanding enzymatic functions and to develop artificially catalytic reaction systems which can exhibit excellent activity and practical usability for syntheses related to preparative oxidation in organic chemistry1]. |
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| Keywords: | Y zeolite phenol hydroxylation |
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