| 含硅芳香二酐的合成及其聚酰亚胺 |
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| 引用本文： | 潘英,林保平,钱鹰,浅井清次,井上真一,冈本弘. 含硅芳香二酐的合成及其聚酰亚胺[J]. 功能高分子学报, 2003, 16(2): 225-228 |
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| 作者姓名： | 潘英 林保平 钱鹰 浅井清次 井上真一 冈本弘 |
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| 作者单位： | 东南大学化学化工系,江苏,南京,210096;爱知工业大学应用化学系,日本,470-0393 |
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| 基金项目： | 东南大学科学基金(编号:9207041140) |
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| 摘 要： | 从4-溴-l,2-二甲苯出发,经过三步反应合成了双-（3,4-苯二甲酸酐)二甲基硅烷单体,总产率为24．7％;由该单体与4,4′-二氨基二苯醚共聚合,经环化脱水反应得含硅聚酰亚胺,并对该共聚物进行了初步表征。
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| 关 键 词： | 含硅芳香二酐 聚酰亚胺 单体 |
| 文章编号： | 1008-9357(2003)02-0225-04 |
| 修稿时间： | 2002-12-13 |
Synthesis of a Silicon-Containing Aromatic Dianhydride and its Polyimide |
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| PAN Ying,LIN Bao-ping,QIAN Ying,Asai Kiyotsugu,Inoue Shin-ichi,Okamoto Hiroshil. Synthesis of a Silicon-Containing Aromatic Dianhydride and its Polyimide[J]. Journal of Functional Polymers, 2003, 16(2): 225-228 |
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| Authors: | PAN Ying LIN Bao-ping QIAN Ying Asai Kiyotsugu Inoue Shin-ichi Okamoto Hiroshil |
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| Abstract: | Monomer bis(3,4-dicarboxyphenyl)dimethylsilane dianhydride was synthesized from 4-bromo-1,2-dimethyl-benzene and dichlorodimethylsilane through Wurtz coupling reaction , oxidization and cyclization reaction with the overall yield of 24. 7% . And bis(3,4-dicarboxyphenyl)dimethylsilane dianhydride was copolymerized with 4,4'-diaminodiphenyl ether in the N.N '-dimethylacetamide . The corresponding polyimide was characterized by FTIR and WAXD as well as UV-Vis . |
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| Keywords: | silicon-containing aromatic dianhydride polyimide monomer |
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