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| 新型多重氮杂杯[4]芳烃衍生物的合成 | |
| 引用本文： | 杨发福,季衍卿,郭红玉,林建荣,彭奇. 新型多重氮杂杯[4]芳烃衍生物的合成[J]. 有机化学, 2006, 26(6): 866-869 |
| 作者姓名： | 杨发福 季衍卿 郭红玉 林建荣 彭奇 |
| 作者单位： | 1. 福建师范大学化学与材料学院,福州,350007 2. 中国科学院福建物质结构研究所,福州,3500022 |
| 基金项目： | 国家自然科学基金(No.20402002)，福建省自然科学重点基金(No.E0220002)资助项目. |
| 摘 要： | 对叔丁基杯[4]芳烃-1,3-二醛基衍生物1与水杨酰肼、烟酰肼、异烟酰肼反应, 合成了具有开链结构新型杯[4]多重氮杂衍生物2a～2c, 产率分别为88%, 85%和90%. 化合物1与乙二酰肼、丙二酰肼、己二酰肼反应, 得到具有桥联结构的新型杯[4]多重氮杂衍生物3a～3c, 产率分别为86%, 89%和90%. 新化合物的结构经元素分析、质谱、核磁共振谱等表征证实, 杯[4]芳烃单元均为1,3-取代且采取锥式构象. |
| 关 键 词： | 杯[4]芳烃 多重氮杂 酰肼 合成 |
| 收稿时间： | 2005-06-17 |
| 修稿时间： | 2005-12-28 |
Syntheses of Novel Calix[4]arene Derivatives with Polyaza Groups |
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| YANG, Fa-Fu,JI, Yan-Qing,GUO, Hong-Yu,LIN, Jian-Rong,PENG, Qi. Syntheses of Novel Calix[4]arene Derivatives with Polyaza Groups[J]. Chinese Journal of Organic Chemistry, 2006, 26(6): 866-869 | |
| Authors: | YANG Fa-Fu JI Yan-Qing GUO Hong-Yu LIN Jian-Rong PENG Qi |
| Affiliation: | 1 College of Chemistry and Materials, Fujian Normal University, Fuzhou 350007;2 State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002 |
| Abstract: | The reaction of p-tert-butylcalix[4]-1,3-substituted benzaldehyde derivative 1 with salicylic hydrazide, nicotinic hydrazide or isonicotinic hydrazide gave a series of novel ring opening calix[4]arene derivatives 2a～2c containing polyaza groups in the yields of 88%, 85% and 90%, respectively. Treatment of compound 1 with oxalyl dihydrazide, malonic dihydrazide and adipic dihydrazide, afforded novel bridged calix[4]arene derivatives 3a～3c substituted with polyaza groups in the yields of 86%, 89% and 90%, respectively. All new compounds were characterized by elemental analyses, ESI-MS, 1H NMR spectra, which indicated that calix[4]arene units were 1,3-substituted pattern with cone conformation. |
| Keywords: | calix[4]arene polyaza hydrazide synthesis |
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