Iron(III) complexes with benzoxazole derivatives |
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| Authors: | Rosalba Pinna Gustavo Ponticelli Francesco Aramu Adriano Delunas Vera Maxia |
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| Institution: | (1) Istituto di Chimica Generale, Inorganica e Analitica, Universita, Via Ospedale, 72, 09124 Cagliari, Italy;(2) Istituto di Fisica Superiore e Gruppo Nazionale di Struttura della Materia del C.N.R., Universita, Via Ospedale, 72, 09124 Cagliari, Italy |
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| Abstract: | Summary Iron(III) complexes of the general formula Fe(L)nX3·mH2O, where L=benzoxazole(benzox), 2-methylbenzoxazole(2-Mebenzox), 2, 5-dimethylbenzoxazole(2, 5-diMebenzox); n=2, 3, 4, 6; X=Cl, Br, NO3 or ClO4; m=0, 1, 2, 5, have been prepared and studied by chemical analysis, magnetic moments, i.r., electronic, Mössbauer spectra and molar conductivity values.The oxazoles are Nring bonded and the complexes are hexacoordinate in the solid state with exception of the five-coordinate Fe(2, 5-diMebenzox)2Br3. |
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