摘 要: | 采用高温固相反应合成CaTiO3∶Pr3 、Zn2TiO4、Ca0.7Zn0.3-xCdxTiO3∶Pr3 (x=0.01,0.03,0.05,0.07,0.09,0.1)红色系列粉末状发光材料。经X射线衍射检测其结构,CaTiO3结构为正交晶系,其结果与JCPDS标准卡(42-423)相符。Zn2TiO4结构属立方晶系,结果与JCPDS标准卡(25-1164)一致。Ca0.7Zn0.3-xCdxTiO3∶Pr3 (x=0.01,0.03,0.05,0.07,0.09,0.1)由两种物相组成,一种为CaTiO3,另一种为Zn2TiO4。检测了材料的激发光谱和发射光谱。发现,在CaTiO3∶Pr3 中加入适量Zn可形成Zn2TiO4相,使材料的激发光谱在324nm附近的吸收增强。少量Cd可进入Zn2TiO4晶格,增强激发光谱在324nm附近的吸收,同时提高发射光谱的强度;但过量的Cd的加入会导致发射光谱强度下降。
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