| 一维链状冠醚配合物:[{Na(18-C-6)}2(H2O)]n[M(SCN)4]n(M=Pd、Pt)的合成与结构 |
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| 引用本文： | 朱德中,宋兴民,窦建民,刘颖,王大奇,雍伟,郑培菊.一维链状冠醚配合物:[{Na(18-C-6)}2(H2O)]n[M(SCN)4]n(M=Pd、Pt)的合成与结构[J].无机化学学报,2002,18(7):697-700. |
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| 作者姓名： | 朱德中 宋兴民 窦建民 刘颖 王大奇 雍伟 郑培菊 |
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| 作者单位： | 1. 聊城师范学院化学系,聊城,252000
2. 复旦大学分析测试中心,上海,200433 |
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| 摘 要： | The reactions of 18-crown-6 with Na2M(SCN)4] (M= Pd,Pt) were studied and the complex 1 {Na(18-C-6)}2(H2O)]nPd(SCN)4]n and complex 2 {Na(18-C-6)}2(H2O)]nPt(SCN)4]n were characterized by ele-mental analysis, IR and X-ray diffraction analysis. The complexes belong to monoclinic, space group P21/n with cell dimensions, 1:a=1.05734(7),b=1.42250(10),c=1.47762(10) nm,β=107.5330(10)°,V=2.1192(2)nm3,Z=2,Dcalcd=1.460g·cm-3,F(000)=964,R1=0.0406,wR2=0.1264 and 2:a=1.05985(19),b=1.4237(3),c=1.4744(3) nm,β=107. 096(3)°, V=2.1264(7)nm3,Z=2,Dcalcd=1.690g·cm-3,F(000)=1028,R1=0.0292,wR2=0.0859. In the solid state, the complexes 1 and 2 show an one-dimensional chain of {Na(18-C-6)}2(H2O)]2+ complex cations and M(SCN)4]2- (M=Pd,Pt) complex anions bridged by Na-N in-teractions.
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| 关 键 词： | 一维链 18-冠-6 Pd、Pt配合物 晶体结构 |
| 修稿时间： | 2001年9月11日 |
One-dimensional Chain Crown Ether Complexes: Syntheses and Crystal Structures of [{Na(18-C-6)}2(H2O)]n[M(SCN)4]n (M=Pd,Pt) |
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| ZHU De-Zhong,SONG Xing-Min,DOU Jian-Min,LIU Ying,WANG Da-Qi,YONG Wei and ZHENG Pei-Ju.One-dimensional Chain Crown Ether Complexes: Syntheses and Crystal Structures of [{Na(18-C-6)}2(H2O)]n[M(SCN)4]n (M=Pd,Pt)[J].Chinese Journal of Inorganic Chemistry,2002,18(7):697-700. |
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| Authors: | ZHU De-Zhong SONG Xing-Min DOU Jian-Min LIU Ying WANG Da-Qi YONG Wei and ZHENG Pei-Ju |
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| Abstract: | |
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| Keywords: | one-dimensional chain 18-crown-6 Pd Pt complexes crystal structure |
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