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Acylative cleavage of aziridines with acid anhydrides catalyzed by Scandium triflate
Authors:J. S. Yadav   B. V. S. Reddy   K. Sadashiv   K. Harikishan  A. V. Narsaiah
Affiliation:

Division of Organic Chemistry, Indian Institute of Chemical Technology, Hyderabad 500007, India

Abstract:
Aziridines smoothly react with acid anhydrides in the presence of a catalytic amount of scandium triflate under mild reaction conditions to afford the corresponding β-aminoacetates, benzoates and propionates in high yields with high regioselectivity.
Keywords:Scandium reagents   Aziridines   Acid anhydrides   β-Aminoesters
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