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| 具有梯形结构钴(Ⅱ)配位聚合物的合成及晶体结构 | |
| 引用本文： | 吴杰颖,潘月礼,张宣军,张明亮,田玉鹏,FUN Hoong-Kun.具有梯形结构钴(Ⅱ)配位聚合物的合成及晶体结构[J].无机化学学报,2003,19(12):1347-1350. |
| 作者姓名： | 吴杰颖 潘月礼 张宣军 张明亮 田玉鹏 FUN Hoong-Kun |
| 作者单位： | 1. 安徽大学化学化工学院,合肥,230039 2. 中国科学技术大学化学系,合肥,230026 3. 安徽大学化学化工学院,合肥,230039;南京大学配位化学国家重点实验室,南京,210093 4. 4X-Ray Crystallography Unit, School of Physics, Universiti Sains Malaysia 11800 USM,Penang, Malaysia |
| 基金项目： | 国家自然科学基金资助项目(No.20071001,50272001)，安徽省自然科学基金资助项目(No.03044701)，马来西亚科技大学研究基金资助项目(R&DNo.305/PFIZIK/61096)。 |
| 摘 要： | Co(NO3)2, N-carbazolyacetic acid and 4,4′-bipyridyl can give rise to a novel coordination polymer CO2(Cabo)2(NO3)2(4,4′-bipy)2]n using a fritted U-tube. Single crystal X-ray diffraction displays in the complex, each Co(Ⅱ) is six-coordinated by two N atoms from different 4,4′-bipyridyl ligands, two O atoms of the bridge from two N-carbazolyacetic acid and two O atoms of one nitrate anion to form a distorted octahedral. Two O atoms of the carboxyl group act as bridge to link two Co(Ⅱ) atoms. The resulting structure is a ladder polymer. CCDC: 211713. |
| 关 键 词： | 钴配合物 梯形分子 咔唑乙酸 4 4′-联吡啶 |
Synthesis and Crystal Structure of a Novel Cobalt(Ⅱ)Coordination Polymer with Molecular Ladder Structure |
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| WU Jie-Ying,PAN Yue-Li,ZHANG Xuan-Jun,ZHANG Ming-Liang,TIAN Yu- Peng and FUN Hoong-Kun.Synthesis and Crystal Structure of a Novel Cobalt(Ⅱ)Coordination Polymer with Molecular Ladder Structure[J].Chinese Journal of Inorganic Chemistry,2003,19(12):1347-1350. | |
| Authors: | WU Jie-Ying PAN Yue-Li ZHANG Xuan-Jun ZHANG Ming-Liang TIAN Yu- Peng and FUN Hoong-Kun |
| Institution: | Department of Chemistry, Anhui University, Hefei 230039,Department of Chemistry, Anhui University, Hefei 230039,Department of Chemistry, University of Science and Technology of China, Hefei 230026,Department of Chemistry, Anhui University, Hefei 230039,Department of Chemistry, Anhui University, Hefei 230039;State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093 and X-Ray Crystallography Unit, School of Physics, Universiti Sains Malaysia 11800 USM, Penang, Malaysia |
| Abstract: | Co(NO3) 2, N-carbazolyacetic acid and 4, 4'-bipyridyl can give rise to a novel coordination polymerCo2(Cabo)2(NO3)2(4, 4'-bipy)2] n using a fritted U-tube. Single crystal X-ray diffraction displays in the complex, each Co (Ⅱ) is six-coordinated by two N atoms from different 4, 4'-bipyridyl ligands, two O atoms of the bridge from two N-carbazolyacetic acid and two O atoms of one nitrate anion to form a distorted octahedral. Two O atoms of the carboxyl group act as bridge to link two Co (Ⅱ) atoms. The resulting structure is a ladder polymer. |
| Keywords: | cobalt complex molecular ladder N-carbazolyacetie acid 4'4-bipyridyl |
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