首页 | 本学科首页   官方微博 | 高级检索  
     


Clean Donor Oxidation Enhances the H2 Evolution Activity of a Carbon Quantum Dot–Molecular Catalyst Photosystem
Authors:Benjamin C. M. Martindale  Evelyne Joliat  Dr. Cyril Bachmann  Prof. Dr. Roger Alberto  Dr. Erwin Reisner
Affiliation:1. http://www‐reisner.ch.cam.ac.uk/;2. Christian Doppler Laboratory for Sustainable SynGas Chemistry, Department of Chemistry, University of Cambridge, Cambridge, UK;3. Department of Chemistry, University of Zürich, Zürich, Switzerland
Abstract:Carbon quantum dots (CQDs) are new‐generation light absorbers for photocatalytic H2 evolution in aqueous solution, but the performance of CQD‐molecular catalyst systems is currently limited by the decomposition of the molecular component. Clean oxidation of the electron donor by donor recycling prevents the formation of destructive radical species and non‐innocent oxidation products. This approach allowed a CQD‐molecular nickel bis(diphosphine) photocatalyst system to reach a benchmark lifetime of more than 5 days and a record turnover number of 1094±61 molH2 (molNi)?1 for a defined synthetic molecular nickel catalyst in purely aqueous solution under AM1.5G solar irradiation.
Keywords:carbon quantum dots  hydrogen evolution  molecular catalysis  photocatalysis  photosensitizers
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号