Methyl, hydrochalcogenido, and phenylchalcogenolate complexes of zinc in a sulfur rich coordination environment: syntheses and structural characterization of the tris(2-mercapto-1-tert-butylimidazolyl)hydroboratozinc complexes [TmBut]ZnMe, [TmBut]ZnEH (E = S, Se) and [TmBut]ZnEPh (E = O, S, Se, Te) |
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| Authors: | Melnick Jonathan G Docrat Arefa Parkin Gerard |
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| Institution: | Department of Chemistry, Columbia University, New York, New York, 10027, USA. |
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| Abstract: | A series of hydrochalcogenido and phenylchalcogenolate complexes of zinc supported by tris(2-mercapto-1-tert-butylimidazolyl)hydroborato ligation, Tm(Bu(t))]ZnEH (E = S, Se) and Tm(Bu(t))]ZnEPh (E = O, S, Se, Te) have been synthesized from Tm(Bu(t))]ZnMe; structural characterization by X-ray diffraction indicates that the variation in Zn-E bonding as a function of the chalcogen is significantly different from that in other series of metal-chalcogenolate compounds. |
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