| Crystal Structure and Molecular Structure of Binuclear Copper（Ⅱ）Complex，［Cu（C_5H_5NO）（C_6H_5COO）_2］_2 |
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| 作者姓名： | Yang Rui-Na Hou Yi-Min Xue Bao-Yu Jin Dou-Man |
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| 作者单位： | Yang Rui-Na; Hou Yi-Min; Xue Bao-Yu; Jin Dou-Man (Henan Institute of Chemistry，Zhengzhou 450003) Chen Liao-Rong; Luo Bao-Sheng(Wuhan University，Wuhan 430072) |
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| 摘 要： | ＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅａｎｄＭｏｌｅｃｕｌａｒＳｔｒｕｃｔｕｒｅｏｆＢｉｎｕｃｌｅａｒＣｏｐｐｅｒ（Ⅱ）Ｃｏｍｐｌｅｘ，［Ｃｕ（Ｃ_５Ｈ_５ＮＯ）（Ｃ_６Ｈ_５ＣＯＯ）_２］_２￥ＹａｎｇＲｕｉ－Ｎａ；ＨｏｕＹｉ－Ｍｉｎ；ＸｕｅＢａｏ－Ｙｕ；Ｊｉ...
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Crystal Structure and Molecular Structure of Binuclear Copper(Ⅱ) Complex, [Cu (C_5H_5NO) (C_6H_5COO)_2]_2 |
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| Yang Rui-Na, Hou Yi-Min, Xue Bao-Yu, Jin Dou-Man.Crystal Structure and Molecular Structure of Binuclear Copper(Ⅱ) Complex, [Cu (C_5H_5NO) (C_6H_5COO)_2]_2[J].Chinese Journal of Structural Chemistry,1995(2). |
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| Authors: | Yang Rui-Na Hou Yi-Min Xue Bao-Yu Jin Dou-Man |
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| Abstract: | At room temperature, dibenzoyl peroxide and pyridine N-oxide reacted with metallic copper powder in a mixed solvent(dichloromethane, trichloromethane and tetrahydrofuran), resulting in a binuclear copper(Ⅱ) complex. Cu (C_5H_5NO)-(C_6H_5COO)_2]_2. The structure of the complex was characterized by elemental analyses.IR spectra and X-ray single crystal analysis. The crystal is triclinic, space group P1,with cell parameters . a= 9. 262(4) ,b= 10. 697(2) , c=10. 881 (3 )A , a=59. 60( 2 ),β= 74. 83 ( 3 ) .Y = 72. 80 ( 2 )°. V= 880. 0 A￣3 . D_c = 1 . 5 20 g/cm￣3 . Z = 1 . μ= 1 2. 7 cm-1, R=0. 044 ,R_w=0. 048 for 3477 reflections with I>3σ(I), M_r=805. 78. Each copper(Ⅱ) atom is coordinated by four bridging bidentate benzoate ligands and one pyridine M-oxide. |
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| Keywords: | crystal structure binuclear copper complex oxidation addition |
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