Preparation and catalytic activity of a new dioxomolybdenum(VI) complex for olefin epoxidation |
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Authors: | Feng-Lan Chai Xiang-Yu Wang Jing-Chao Tao |
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Affiliation: | (1) Department of Chemistry, Zhengzhou University, Zhengzhou, 450052, P.R.China |
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Abstract: | A novel dioxomolybdenum(VI) complex of ferrocenyliminoalcoholate was easily prepared by the reaction of the ferrocenyl-containing iminoalcohol and MoO2Cl2 (THF)2 using THF as solvent. The sample was characterized by FT-IR, 1 H NMR, elemental analysis and UV-Vis. The complex exhibited an efficient, selective catalytic performance for styrene and cyclohexene epoxidation. |
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Keywords: | Ferrocenyl epoxidation molybdenum |
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