| Synthesis and Crystal Structure of N,N′-Bis-[3-chloro-5-S-(l-menthyloxy)-2(5H)-4-furanon-yl]-propane-1,3-diamine |
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| 引用本文： | 宋秀美,汪朝阳,莫阳青,毛郑州.Synthesis and Crystal Structure of N,N′-Bis-[3-chloro-5-S-(l-menthyloxy)-2(5H)-4-furanon-yl]-propane-1,3-diamine[J].结构化学,2009,28(5). |
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| 作者姓名： | 宋秀美 汪朝阳 莫阳青 毛郑州 |
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| 作者单位： | School of Chemistry and Environment, South China Normal University, Guangzhou 510006, China
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| 基金项目： | 国家自然科学基金，广东省自然科学基金 |
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| 摘 要： | The title compound,N,N′-bis-3-chloro-5-S-(l-menthyloxy)-2(5H)-4-furanon-yl]-propane-1,3-diamine(C31H48Cl2N2O6,Mr = 615.61),has been synthesized and characterized by IR,1H NMR,MS,elemental analysis and single-crystal X-ray diffraction.The crystal crystallizes in the monoclinic system,space group C2 with a = 16.1091(4),b = 11.1880(3),c = 19.2854(5) ,β = 106.297(2)°,V = 3336.12(15) 3,Z = 4,Dc = 1.226 mg/m3,μ = 0.237 mm-1,F(000) = 1320,the final R = 0.0531 and wR = 0.0700 for 2760 observed reflections(I > 2σ(I)).X-ray analysis reveals that the title compound possesses four rings:two chiral five-membered furanone rings and two six-membered cyclohexane rings with chair conformation,containing eight chiral centers:C2(S),C3(R),C5(R),C10(S),C18(S),C21(R),C22(S) and C25(R).The structure is stabilized by N-H…O hydrogen bonding interaction.
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| 关 键 词： | 2（5H）-furanone 1 3-propanediamine synthesis crystal structure |
Synthesis and Crystal Structure of N,N'-Bis-[3-chloro-5-S-(l-menthyloxy)-2(5H)-4-furanon-yl]-propane-1,3-diamine |
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| SONG Xiu-Mei,WANG Zhao-Yang,MO Yang-Qing,MAO Zheng-Zhou.Synthesis and Crystal Structure of N,N''-Bis-[3-chloro-5-S-(l-menthyloxy)-2(5H)-4-furanon-yl]-propane-1,3-diamine[J].Chinese Journal of Structural Chemistry,2009,28(5). |
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| Authors: | SONG Xiu-Mei WANG Zhao-Yang MO Yang-Qing MAO Zheng-Zhou |
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| Institution: | School of Chemistry and Environment, South China Normal University, Guangzhou 510006, China |
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| Abstract: | The title compound, N,N'-bis-3-chloro-5-S-(l-menthyloxy)-2(5H)-4-furanon-yl]-propane-1,3-diamine (C31H48Cl2N2O6, Mr = 615.61), has been synthesized and characterized by IR, 1H NMR, MS, elemental analysis and single-crystal X-ray diffraction. The crystal crystallizes in the monoclinic system, space group C2 with a = 16.1091(4), b = 11.1880(3), c = 19.2854(5) A, β = 106.297(2)°, V = 3336.12(15) A3, Z= 4, Dc = 1.226 mg/m3,μ = 0.237 mm-1, F(000) = 1320, the final R = 0.0531 and wR = 0.0700 for 2760 observed reflections (I ＞ 2σ(I)). X-ray analysis reveals that the title compound possesses four rings: two chiral five-membered furanone rings and two six-membered cyclohexane rings with chair conformation, containing eight chiral centers: C2(S), C3(R), C5(R), bonding interaction. |
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| Keywords: | 2(SH)-furanone 1 3-propanediamine synthesis crystal structure |
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