| 邻羧基苯甲酰二茂铁钠的合成、晶体结构及电化学性质 |
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| 引用本文： | 李子峰,刘淑敏,吴静霞,李纲.邻羧基苯甲酰二茂铁钠的合成、晶体结构及电化学性质[J].化学研究,2008,19(2):51-54. |
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| 作者姓名： | 李子峰 刘淑敏 吴静霞 李纲 |
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| 作者单位： | 郑州大学,化学系,河南,郑州,450052 |
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| 基金项目： | 国家自然科学基金
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河南省教育厅科研项目 |
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| 摘 要： | 参照文献方法合成了邻羧基苯甲酰二茂铁钠，首次培养得到了它的单晶．发现在其固态结构中，邻羧基苯甲酰二茂铁阴离子与四水合钠阳离子通过分子内氢键相互作用；分子间的氢键又把多个二茂铁衍生物分子连接成二维的网状结构．研究了标题化合物在甲醇溶液中的电化学性质．
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| 关 键 词： | 邻羧基苯甲酰二茂铁钠 晶体结构 电化学 |
Synthesis,Crystal Structure and Electronic Property of o-Ferrocenylcarbonyl Benzoic Acid Sodium |
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| LI Zi-feng,LIU Shu-min,WU Jing-xia,LI Gang.Synthesis,Crystal Structure and Electronic Property of o-Ferrocenylcarbonyl Benzoic Acid Sodium[J].Chemical Research,2008,19(2):51-54. |
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| Authors: | LI Zi-feng LIU Shu-min WU Jing-xia LI Gang |
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| Institution: | (Department of Chemistry, Zhengzhou University, Zhengzhou 450052, Henan, China) |
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| Abstract: | The ferrocenyl compound,o-ferrocenylcarbonyl benzoic acid sodium(C36H44Fe2Na2O15,Mr = 874.39) was prepared by the literature method,and was structurally characterized by means of X-ray single-crystal diffraction.It crystallizes in monoclinic,space group C2/c with a = 3.7687(9),b =0.9212(2),c = 1.1630(3) nm,β= 102.322(2)(°),V = 3.8749(15) nm3,Z = 4,Dc = 1.499 Mg/m3,F(000) = 1 816.the final R1 = 0.0324 and wR2 = 0.084 3 for 4 443 observed reflections with I > 2σ(I).In the compound,the o-FcCOC6H4COO-anion links the Na(H2O)4]+ cation with intramolecular H-bonds.Furthermore,the compounds are joined together by intermolecular H-bonds.The electrochemical property of the title compound was investigated in methanol solution. |
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| Keywords: | o-ferrocenylcarbonyl benzoic acid sodium crystal structure electrochemical property |
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