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Patterned growth of large oriented organic semiconductor single crystals on self-assembled monolayer templates
Authors:Briseno Alejandro L  Aizenberg Joanna  Han Yong-Jin  Penkala Rebecca A  Moon Hyunsik  Lovinger Andrew J  Kloc Christian  Bao Zhenan
Affiliation:Department of Chemistry and Biochemistry, University of California-Los Angeles, Los Angeles, California 90095, USA.
Abstract:This work demonstrates a method for inducing site-specific nucleation and subsequent growth of large oriented organic semiconductor single crystals using micropatterned self-assembled monolayers (SAMs). We demonstrate growth of oriented, patterned, and large organic semiconductor single crystals for potential use in organic electronic devices. The control over multiple parameters in a single system has not yet been reported. The ability to control various aspects of crystal growth in one system provides a powerful technique for the bottom-up fabrication of organic single-crystal semiconductor devices.
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