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Voltammetric Determination of 3‐Nitrofluoranthene and 3‐Aminofluoranthene at Boron Doped Diamond Thin‐Film Electrode
Authors:Karel Cizek  Jiri Barek  Jan Fischer  Karolina Peckova  Jiri Zima
Affiliation:Charles University in Prague, Faculty of Science, Department of Analytical Chemistry, UNESCO Laboratory of Environmental Electrochemistry, 128?43 Prague 2, Czech Republic
Abstract:The voltammetric behavior of 3‐nitrofluoranthene and 3‐aminofluoranthene was investigated in mixed methanol‐water solutions by differential pulse voltammetry (DPV) at boron doped diamond thin‐film electrode (BDDE). Optimum conditions have been found for determination of 3‐nitrofluoranthene in the concentration range of 2×10?8–1×10?6 mol L?1, and for determination 3‐aminofluorathnene in the concentration range of 2×10?7–1×10?5 mol L?1, respectively. Limits of determination were 3×10?8 mol L?1 (3‐nitrofluoranthene) and 2×10?7 mol L?1 (3‐aminofluoranthene).
Keywords:Boron doped diamond thin‐film electrode  Differential pulse voltammetry  3‐Nitrofluoranthene  3‐Aminofluoranthene
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