A New ent‐Kaurane Diterpene from Stems of Alibertia macrophylla K. Schum. (Rubiaceae) |
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Authors: | Viviane Cândida da Silva Andréia de Oliveira Faria Vanderlan da Silva Bolzani Márcia Nasser Lopes |
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Affiliation: | 1. Departamento de Química Organica, Instituto de Química, UNESP ‘Júlio de Mesquita Filho', C.P. 355, CEP 14801‐970, Araraquara, S?o Paulo, Brazil, (phone: +55‐16‐33016662;2. fax: +55‐16‐33016692) |
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Abstract: | Phytochemical investigations of the stems of a specimen of Alibertia macrophylla led to the isolation and characterization of the new diterpene ent‐kaurane‐2β,3α,16α‐triol ( 1 ), along with triterpenes 2 – 8 , iridoids 9 – 12 , and phenolic acids 13 – 15 . The structure of 1 was established based on spectroscopic studies (1H‐ and 13C‐NMR, IR, and HR‐ESI‐MS). This is the first report of the isolation of a diterpene from the Alibertia genus in Rubiaceae. |
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Keywords: | Alibertia macrophylla Diterpenes Kauranes |
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