| 红外光谱法观察二茂镧系氯化物与氧及水蒸气的反应 |
| |
| 引用本文： | 吴天明,钱长涛,聂崇实.红外光谱法观察二茂镧系氯化物与氧及水蒸气的反应[J].无机化学学报,1993,9(4):427-430. |
| |
| 作者姓名： | 吴天明 钱长涛 聂崇实 |
| |
| 作者单位： | 中国科学院上海有机化学研究所 上海200032
(吴天明，钱长涛)，中国科学院上海有机化学研究所 上海200032(聂崇实) |
| |
| 基金项目： | 国家自然科学基金资助项目 |
| |
| 摘 要： | 用实时红外光谱法在特制的收池中分别观察了一些二茂镧系氯化物Ｃｐ２ＬｎＣｌ（Ｃｐ＝Ｃ５Ｈ５，Ｌｎ＝Ｈｏ，Ｇｄ，Ｌｕ）和Ｃｐ＇Ｌｕ（Ｃｐ＝Ｃ５Ｈ４ＣＨ２ＯＣＨ３）与干燥氧气及水蒸气的反应，结果证实这些二茂镧系配合物在室温干燥氧气氛中很稳定，但在水蒸气中很快水蒸气的反应，结果证实这些二茂镧系配合物在室温干燥氧气氛中很稳定，但在水蒸气中很快水解。从水解反应的最初始阶段和较后期采得的红外光谱提示可能存在...
|
| 关 键 词： | 氯化物 水解 有机镧化合物 |
| 收稿时间： | 1992/8/14 0:00:00 |
STUDIES ON THE REACTION OF LANTHANOCENE CHLORIDES WITH OXYGEN AND WATER VAPOR BY IN SITU INFRARED SPECTROSCOPY |
| |
| Wu Tianming,Qian Changtao and Nie Chongshi.STUDIES ON THE REACTION OF LANTHANOCENE CHLORIDES WITH OXYGEN AND WATER VAPOR BY IN SITU INFRARED SPECTROSCOPY[J].Chinese Journal of Inorganic Chemistry,1993,9(4):427-430. |
| |
| Authors: | Wu Tianming Qian Changtao and Nie Chongshi |
| |
| Institution: | Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032,Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032 and Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032 |
| |
| Abstract: | The reaction of some lanthanocene complexes Cp2LnCl(Cp = C5HS-, Ln= Ho, Gd, Lu) and Cp'LuCl (Cp'= C5H4CH2CH2OCH3) with dry oxygen and water vapor were observed respectively at room temperature by in-situ IR spectroscopy in a special designed cell. It evidently indicates that these lanthanoccnes are stable in dry oxygen atmosphere, but hydrolyzed in water vapor rapidly. The IR spectra collected in the very starting and later stage of the hydrolysis reaction imply that some intermediate compounds Cp2LnOH and CpLn(OH)Cl may exist. |
| |
| Keywords: | hydrolysis of lanthanocene chloride in-situ infrared spectroscopy |
| 本文献已被 CNKI 维普 等数据库收录！ |
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
| 点击此处可从《无机化学学报》下载免费的PDF全文 |
