Novel Lewis-base ionic liquids replacing typical anions |
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| Authors: | Masahiro Yoshizawa-Fujita Katarina Johansson Douglas R. MacFarlane |
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| Affiliation: | a School of Chemistry, Monash University, Wellington Road, Clayton VIC 3800, Australia
b Department of Materials Engineering, Australian Centre of Excellence in Electromaterials Science (ACES), Monash University, Wellington Road, Clayton VIC 3800, Australia |
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| Abstract: | We have synthesized two kinds of new Lewis-base ionic liquids (ILs); one is based on the relatively strong Lewis basic acetate anion, and the other is a salt composed of a mono-alkylated diamine such that the Lewis base site is incorporated in the cation. 1-Octyl-4-aza-1-azonia-bicyclo[2.2.2]octane bis(trifluoromethanesulfonyl)amide, [C8dabco]TFSA, and N-butyl-N-methylpyrrolidinium acetate, [p1,4]OAc, melted into fluid liquids at 26 and 81 °C, respectively. The thermal decomposition of [p1,4]OAc started at around 150 °C, whereas the thermal stability of [C8dabco]TFSA was almost equal to that of typical TFSA-based ILs in spite of the Lewis base site. This suggests that if the Lewis base site is incorporated into the cation the IL can maintain higher thermal stability. In addition, as a further result of the presence of the basic nitrogen, [C8dabco]TFSA can dissolve hydrated Cu(NO3)2 whereas the other TFSA-based ILs cannot. |
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| Keywords: | Ionic liquids Lewis base Nucleophilicity Pyrrolidinium salts |
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