Suzuki coupling reactions of 2,4,6-trialkoxyphenylboronic acids with enol triflates: asymmetric synthesis of a lactone template for calyxin assemblage |
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Authors: | Sidika Polat Cakir |
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Institution: | Department of Chemistry, Mississippi State University, Mississippi State, MS 39762, USA |
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Abstract: | Suzuki coupling reactions between 2,4,6-trialkoxyphenylboronic acids and enol triflates have been found to occur in excellent yield, while the use of an enol tosylate failed to give any of the desired product. This coupling reaction has led to the synthesis of a lactone which could serve as a precursor to several calyxin analogues. |
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Keywords: | Calyxins Epicalyxins Suzuki coupling Trialkoxyphenylboronic acids |
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