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Suzuki coupling reactions of 2,4,6-trialkoxyphenylboronic acids with enol triflates: asymmetric synthesis of a lactone template for calyxin assemblage
Authors:Sidika Polat Cakir
Institution:Department of Chemistry, Mississippi State University, Mississippi State, MS 39762, USA
Abstract:Suzuki coupling reactions between 2,4,6-trialkoxyphenylboronic acids and enol triflates have been found to occur in excellent yield, while the use of an enol tosylate failed to give any of the desired product. This coupling reaction has led to the synthesis of a lactone which could serve as a precursor to several calyxin analogues.
Keywords:Calyxins  Epicalyxins  Suzuki coupling  Trialkoxyphenylboronic acids
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