Iodofluorination of alkenes and alkynes promoted by iodine and 4-iodotoluene difluoride |
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Authors: | Pellegrino Conte |
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Affiliation: | Facoltà di Agraria, Università di Napoli ‘Federico II’, I-80055-Portici (NA), Italy |
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Abstract: | It was found that a mixture of molecular iodine and 4-iodotoluene difluoride are useful to generate in situ the couple ‘IF’ that was able to add in a Markovnikov fashion and with prevalent anti-stereoselectivity to various alkenes and alkynes. |
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Keywords: | Hypervalent iodine Electrophilic iodination Fluoroiodoalkanes Fluoroiodoalkenes |
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