Stereoselective synthesis of 3,4-trans-disubstituted pyrrolidines and cyclopentanes via intramolecular radical cyclizations mediated by CAN |
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| Authors: | Vijay Nair Kishor Mohanan Eringathodi Suresh |
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| Institution: | a Organic Chemistry Division, Regional Research Laboratory (CSIR), Trivandrum, India
b Central Salt and Marine Chemicals Research Institute (CSIR), Bhavnagar 364 002, India |
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| Abstract: | The stereoselective intramolecular cyclizations of bis(cinnamyl)tosylamides and dimethyl bis(cinnamyl)malonates mediated by cerium(IV) ammonium nitrate leading to the synthesis of 3,4-trans-disubstituted pyrrolidines and cyclopentanes are described. |
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