An unexpected palladium-catalyzed cyclization of bis-hydroxy allylic alcohols to dioxabicyclo[2.2.2]octanes |
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| Authors: | Anna Zawisza |
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| Affiliation: | Laboratoire de Synthèse Asymétrique, Associé au CNRS, UMR 5181, CPE Lyon, Université Claude Bernard Lyon 1, 43, Boulevard du 11 Novembre 1918, 69622 Villeurbanne Cédex, France |
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| Abstract: | ![]()
The palladium(II)-catalyzed cyclization of bis-hydroxy allylic alcohols afforded quantitatively a mixture of (3-alkyl-5-vinyltetrahydrofuran-3-yl)methanol and 4-alkyl-1-methyl-2,6-dioxabicyclo[2.2.2]octane. |
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| Keywords: | Palladium catalyst Cyclization 2,6-Dioxabicyclo[2.2.2]octane Tetrahydrofuran |
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