Enantiospecific synthesis of tricyclo[5.2.1.0]decanes via acid catalysed rearrangement of isotwistanes |
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| Authors: | A. Srikrishna G. Satyanarayana P. Ravi Kumar |
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| Affiliation: | Department of Organic Chemistry, Indian Institute of Science, Bangalore 560012, India |
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| Abstract: | ![]()
An acid catalysed rearrangement was employed for the enantiospecific conversion of isotwistanol to tricyclo[5.2.1.04,8]decanes, which provided support for the proposed biosynthesis of allopupukeananes from pupukeananes. The strategy has been further extended to the enantiospecific synthesis of a homobrexane. |
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| Keywords: | Molecular rearrangement Isotwistanes Pupukeananes Allopupukeanane |
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