An efficient palladium-catalyzed Heck coupling of aryl chlorides with alkenes |
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Authors: | Chenyi Yi |
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Affiliation: | Department of Chemistry, Tsinghua University, Innovative Catalysis Program, Key Laboratory of Organic Optoelectronics and Molecular Engineering of Ministry of Education, Beijing 100084, China |
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Abstract: | Catalyst system PdCl2(PCy3)2/Cs2CO3 in dioxane was found to be the efficient catalyst system for Heck cross-coupling reactions of deactivated, neutral, and activated aryl chlorides with a variety of alkenes under mild conditions to afford selectively E-arylated alkenes in good to excellent yields. |
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Keywords: | Alkene Aryl chloride Catalysis Heck coupling Palladium |
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