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Direct Barbier-type allylation of aromatic acetals and dioxolanes in the presence of β-cyclodextrin in water
Authors:K Surendra
Institution:Organic Chemistry Division-I, Indian Institute of Chemical Technology, Hyderabad 500 007, India
Abstract:A new and convenient procedure for the synthesis of homoallylic alcohols directly from aromatic acetals and dioxolanes has been developed with very good yields under biomimetic conditions using a Zn-mediated Barbier-type allylation in the presence of β-cyclodextrin in water.
Keywords:Acetals  Allylation  Allyl bromide  Zinc  β-Cyclodextrin  Water
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