Determination of the apparent standard potential of the Dy/Dy(Ⅲ) system in the LiCl-KCl eutectic |
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作者姓名: | CHANG Kai-Guo LU Xiang-Ping DU Fu-Ying ZHAO Min-ShouChangchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun Jilin 130022 China |
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作者单位: | CHANG,Kai-Guo LU,Xiang-Ping DU,Fu-Ying ZHAO,Min-ShouChangchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun,Jilin 130022 China |
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基金项目: | Project supported by Science Foundation of Laboratory of Rare Earth Chemistry and Physics. |
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摘 要: | The apparent standard potential of Dy/Dy(III) system in the LiCl-KCl eutectic has been determined by the logarithmic analysis of the semi-integrals of voltammograms, logarithmic analysis of chronopotentiograms and the open circuit potentiometry. The dysprosium equilibrium potentiab for various concentration of dysprosium chloride in the LiCl-KCl eutectic melt between 400-500℃ were first determined experimentally, and the apparent standard potential of this system and its temperature dependance have been calculated.
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