Engineering silver(I) coordination networks through hydrogen bonding |
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Authors: | Burchell Tara J Eisler Dana J Puddephatt Richard J |
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Affiliation: | Department of Chemistry, University of Western Ontario, London, Ontario, Canada N6A 5B7. |
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Abstract: | The silver(I) coordination networks [Ag2(mu-O2CCF3)2(mu-NN)2](infinity) exist as a polymer of macrocycles or a double-stranded polymer when NN = 1,2-C6H4[NHC(O)-4-C5H4N]2 or 1,2-C6H4[NHC(O)-3-C5H4N]2, respectively. Crystal engineering of the polymers is achieved through interchain hydrogen bonds. |
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