Reversible water uptake by a stable imine-based porous organic cage |
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| Authors: | Hasell Tom Schmidtmann Marc Stone Corinne A Smith Martin W Cooper Andrew I |
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| Affiliation: | Department of Chemistry and Centre for Materials Discovery, University of Liverpool, Crown Street, Liverpool L69 7ZD, UK. |
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| Abstract: | A crystalline porous organic cage molecule, CC3, is shown to adsorb up to 20.1 wt% water reversibly. This was confirmed by both gravimetric sorption and by crystallographic analysis. Crystals of CC3 are stable in boiling water for at least 4 h. The surprising chemical and supramolecular stability of these imine-based molecular crystals suggests scope for practical applications in humid environments. |
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