Addition compounds of nucleophiles and 3-ethylthio-6-oxo-6H-1,2-dithiolo[4,3-c]1,2-dithiolium tetrafluoroborate. Synthesis of 3H,6H-1,2-dithiolo[4,3-c]1,2-dithiole-3-one-6-thione |
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Authors: | Bernd Kordts Andreas M Richter Egon Fanghänel |
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Institution: | (1) Sektion Chemie, Technische Hochschule Carl Schorlemmer Leuna-Merseburg, Otto-Nuschke-Straße, D-O-4200 Merseburg, Germany |
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Abstract: | Summary A smooth method of synthesizing 3H, 6H-1,2-dithiolo4,3-c]1,2-dithiole-3,6-dithione (3), and also its partial desulfuration to yield 3H, 6H-1,2-dithiolo4,3-c]1,2-dithiole-3-one-6-thione (4) is presented. The ethylation product5 of the monothione4 reacts with various nucleophilic reagents to form remarkably stable adducts. The adducts of5 with methanol,tert-butyl mercaptan, and with aniline could be isolated and characterized by their1H-NMR spectra.
Anlagerungsverbindungen von Nukleophilen an 3-Ethylthio-6-oxo-6H-1,2-dithiolo4,3-c]1,2-dithioliumtetrafluoroborat. Synthese von 3H,6H-1,2-Dithiolo4,3-c]1,2-dithiol-3-on-6-thion Zusammenfassung Eine glatte Synthese für 3H,6H-1,2-Dithiolo4,3-c]1,2-dithiol-3,6-dithion (3) und für dessen partielle Entschwefelung zu 3H,6H-1,2-Dithiolo4,3-c]1,2-dithiol-3-on-6-thion (4) wird angegeben. Das Ethylierungsprodukt5 des Monothions4 reagiert mit unterschiedlichen Nukleophilen zu bemerkenswert stabilen Addukten. Die Addukte mit Methanol,tert.-Butylmercaptan und mit Anilin wurden isoliert und durch ihr1H-NMR-Spektrum charakterisiert. |
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Keywords: | 3H 6H-1 2-Dithiolo[4 3-c]1 2-dithiole-3 6-dithione synthesis and partial desulfuration of 3H 6H-1 2-Dithiolo[4 3-c]1 2-dithiole-3-one-6-thione synthesis and alkylation of 3-Ethylthio-6-oxo-6H-1 2-dithiolo[4 3-c]1 2-dithiolium tetrafluoroborate synthesis and formation of adducts with nucleophiles of |
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