| 烯丙基保护基在多羟基化合物中的应用 |
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| 引用本文： | 刘煜,卢志云,邢孔强,谢明贵.烯丙基保护基在多羟基化合物中的应用[J].化学研究与应用,2001,13(1):39-45. |
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| 作者姓名： | 刘煜 卢志云 邢孔强 谢明贵 |
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| 作者单位： | 1. 四川大学化学学院,
2. 琼州大学化学系, |
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| 摘 要： | 烯丙基保护基由于能够在温和的反应条件下，在羟基、氨基等基团中引入和脱除，并且具有很好的区域选择性和化学选择性，因此被广泛应用于有机合成中。本文介绍了烯丙基保护基的发展历史，综述了烯丙保护基对多羟基化合物中不同羟基的选择性保护应用，并阐述了烯丙保护基的引入和脱除的机理及方法。
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| 关 键 词： | 烯丙基保护基 多羟基化合物 保护基引入 保护基脱除 选择性 |
| 文章编号： | 1004-1656(2001)01-0039-07 |
| 修稿时间： | 2000年11月29 |
THE USE OF ALLYLICGROUP AS A PROTECTING GROUP FOR THE MULTIHYDROXY COMPOUNDS |
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| LIU yu ,LU Zhi yun ,XING Kong qiang ,XIE Ming gui.THE USE OF ALLYLICGROUP AS A PROTECTING GROUP FOR THE MULTIHYDROXY COMPOUNDS[J].Chemical Research and Application,2001,13(1):39-45. |
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| Authors: | LIU yu LU Zhi yun XING Kong qiang XIE Ming gui |
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| Institution: | LIU yu 1,2,LU Zhi yun 1,XING Kong qiang 2,XIE Ming gui 1 |
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| Abstract: | The allylic protecting group,which could be formed and removed to hydroxy and amino groups under mild reaction conditions with good regionselectivity and chemicoselectivity,has been used widely in organic synthesis recently.In this paper,the development of the allylic group used as protecting group has been introduced,the selective protection of allylic to different hydroxy groups of multihydroxy compounds has been reviewed,the mechanisms and methods of formation and removal of allylic protecting groups has been expounded. |
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| Keywords: | allylic protecting groups multihydroxy compounds formation of protecting group removal of protecting group selectivity |
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