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Michael additions to steroidal 1-ene-3-ones |
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| Authors: | Malcolm M Campbell Veerappa B Jigajinni RH Wightman |
| Institution: | Department of Chemistry, Herriot-Watt University, Riccarton, Currie, Edinburgh EH14 4AS U.K. |
| Abstract: | A reactivity pattern was established for Michael addition of aryl thiolates to 17-acetoxy 5α-androst-1-en-3-one. An abnormal bicyclic bridged adduct was obtained in the reaction of thiourea. |
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