Carboncarbon bond cleavage during lithium aluminum hydride reduction of a terminal propargyl alcohol期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Carboncarbon bond cleavage during lithium aluminum hydride reduction of a terminal propargyl alcohol

Authors:	David E. Cane Radha Iyengar

Affiliation:	Department of Chemistry, Brown University, Providence, Rhode Island 02912 U.S.A.

Abstract:	Reduction of dehydronerolidol with lithium aluminum hydride in the presence of sodium methoxide gave, in addition to the expected nerolidol, geranyl acetone. Labeling experiments established that the C-1 methyl of geranyl acetone is derived from one of the carbons of the acetylene.

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