Anti-[3.3]metacyclophane quinhydrones: synthesis,charge-transfer absorption and thermal rearrangement to syn-stereoisomers |
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Authors: | Heinz A. Staab Annelie Döhling |
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Affiliation: | Abteilung Organische Chemie Max-Planck-Institut für medizinische Forschung Jahnstrasse 29, D-6900 Heidelberg Germany |
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Abstract: | The synthesis of -[3.3]metacyclophane quinhydrones and their thermal rearrangement to -stereoisomers are described. Charge-transfer absorptions are discussed under the aspect of different donor-acceptor orientations. |
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