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Anti-[3.3]metacyclophane quinhydrones: synthesis,charge-transfer absorption and thermal rearrangement to syn-stereoisomers
Authors:Heinz A. Staab  Annelie Döhling
Affiliation:Abteilung Organische Chemie Max-Planck-Institut für medizinische Forschung Jahnstrasse 29, D-6900 Heidelberg Germany
Abstract:
The synthesis of anti-[3.3]metacyclophane quinhydrones and their thermal rearrangement to syn-stereoisomers are described. Charge-transfer absorptions are discussed under the aspect of different donor-acceptor orientations.
Keywords:
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