| 胍盐键合型聚氨酯涂料的制备及其抗菌防霉性能 |
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| 引用本文： | 陈飞燕,李宗亮,陈洁,李田泉,管涌,郑安呐. 胍盐键合型聚氨酯涂料的制备及其抗菌防霉性能[J]. 功能高分子学报, 2017, 30(3). DOI: 10.14133/j.cnki.1008-9357.2017.03.012 |
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| 作者姓名： | 陈飞燕 李宗亮 陈洁 李田泉 管涌 郑安呐 |
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| 作者单位： | 华东理工大学材料科学与工程学院,上海先进聚合物材料重点实验室,超细材料制备与应用教育部重点实验室,上海 200237 |
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| 基金项目： | 上海市重点学科建设项目，科技部支撑计划 |
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| 摘 要： | 采用化学键合的方式将聚六亚甲基盐酸胍(PHMG)键合到聚氨酯(PU)分子链上,制得抗菌PU涂料PU-PHMG。利用红外光谱(FT-IR)、阿贝折射仪、原子力显微镜(AFM)等对其结构与性能进行了表征,用振荡法、抑菌圈法等对其抗菌性能进行了测试,同时探究了PHMG的质量分数对PU涂料各项性能的影响。研究表明:当PHMG的质量分数为1.0%时,PHMG的键合效率达到93.59%,对大肠杆菌和金黄色葡萄球菌的抑菌率达到99.5%以上,证明PU-PHMG具有优异持久的抗菌性能。此外,该涂料还兼具优异的防霉性能和力学性能。
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| 关 键 词： | 胍盐齐聚物 聚氨酯涂料 抗菌 防霉 |
Preparation of Polyurethane Coatings Bonded with Guanidinium Oligomer and Their Antibacterial and Mould-Proof Performance |
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| CHEN Fei-yan,LI Zong-liang,CHEN Jie,LI Tian-quan,GUAN Yong,ZHENG An-na. Preparation of Polyurethane Coatings Bonded with Guanidinium Oligomer and Their Antibacterial and Mould-Proof Performance[J]. Journal of Functional Polymers, 2017, 30(3). DOI: 10.14133/j.cnki.1008-9357.2017.03.012 |
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| Authors: | CHEN Fei-yan LI Zong-liang CHEN Jie LI Tian-quan GUAN Yong ZHENG An-na |
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| Abstract: | Antibacterial and mould-proof polyurethane coatings (PU-PHMG) were prepared via chemically bonding polyurethane (PU) with polyhexamethylene guanidine (PHMG) .The molecular structure and performances of the products were characterized by Fourier Transform Infrared Spectroscopy (FT-IR) , Abbe Refractometer and Atomic Force Microscope (AFM ) ,etc .Properties of PU coatings affected by PHMG mass fraction was investigated . Results showed that when the mass fraction of PHMG was 1 .01% ,the bonding efficiency reached 93 .59% ,the inhibition rate against E .coli and S . aureus was above 99 .5% . Then , the durabily antibacterial property of PU-PHMG was proved . Moreover , the antibacterial coating exhibited excellent performance of mould-proof and mechanical properties . |
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| Keywords: | guanidinium oligomer polyurethane coating antibacterial mould-proof |
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