| 键联环糊精、糖苷的卟啉及金属卟啉的合成 |
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| 引用本文： | 李早英,李聪,李立,王铁锋.键联环糊精、糖苷的卟啉及金属卟啉的合成[J].高等学校化学学报,2000,21(6):840-843. |
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| 作者姓名： | 李早英 李聪 李立 王铁锋 |
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| 作者单位： | 武汉大学化学系, 武汉 430072 |
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| 基金项目： | 湖北省自然科学基金 !(批准号 :98J0 43 )，国家自然科学基金! (批准号 :2 9972 0 3 5 ) |
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| 摘 要： | 全甲基化-6-羟基-β-环糊精(PMβ-CD-CH2OH)在N2气流下与三氟甲基磺酸酐反应得到全甲基化-6-三氟甲基磺酸酯-β-环糊精(PMβ-CD-CH2OTf)(6).6分别与5-(p-氨基苯基)-10,15,20-三苯基镍(钌羰基)卟啉NiTPNH2P](2)和Ru(CO)TPNH2P](3)缩合得到化合物7和8.1-溴-2,3,4,6-O-乙酰基-α-D-葡萄糖(4)和1-溴-2,3,5-O-乙酰-β-D-呋喃糖(5)分别与H2TPNH2P(1)反应得到化合物9和10.新化合物6-10经IR,UV-Vis,1HNMR和元素分析确证,其中化合物6由MS谱进一步确定.
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| 关 键 词： | &beta -环糊精 糖苷 金属卟啉 合成 |
| 收稿时间： | 1999-08-02 |
Synthesis of β-Cyclodextrin and Glucoside Compounds-bonded Porphyrins and Metal Porphyrins |
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| LI Zao-Ying,LI Cong,LI Li,WANG Tie-Feng.Synthesis of β-Cyclodextrin and Glucoside Compounds-bonded Porphyrins and Metal Porphyrins[J].Chemical Research In Chinese Universities,2000,21(6):840-843. |
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| Authors: | LI Zao-Ying LI Cong LI Li WANG Tie-Feng |
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| Institution: | Department of Chemistry, Wuhan University, Wuhan 430072, China |
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| Abstract: | The reaction of mono-6-hydroxy permethylated β-cyclodextrin(PM β-CD-CH2OH) with trifluoromethanesulforic anhydride under N2 gave mono 6 trifluoromethanesulfonate permethylated β-cyclodextrin(6). Compound 6 reacted with 5-( p aminophenyl)-10,15,20-triphenyl nickel porphyrin NiTPNH2 P](2) or 5-( p aminophenyl)10,15,20 triphenyl carbonyl ruthenium porphyrinRu(CO)TPNH2 P](3) to produce complexes 7 and 8. 1-Bromo-2,3,5-Oacetyl-β-D-furanoside(4) and 1-bromo-1,2,3,4,6-Oacetyl-α-D-pyranoglucoside(5) respectively reacted with H2TPNH2 P(1) to afford compounds 9 and 10. The new compounds 6-10 were identified by IR, UV-Vis, 1H NMR, elemental analysis, in which compound 6 was determined by MSspectra. |
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| Keywords: | Cyclodextrin Glucoside compounds Metal porphyrins Synthesis |
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