On the mechanism of allylic alkylations catalyzed by palladium |
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Authors: | Barry M. Trost Norman R. Schmuff |
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Affiliation: | McElvain Laboratories of Organic Chemistry, Department of Chemistry University of Wisconsin, Madison, WI 53706 USA |
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Abstract: | Reults are reported indicating the intermediacy of a symmetrical π-allyl species in the alkylation of an allylic lactone. A previous report indicating that another mechanism was operative is disputed. |
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