Kinetics and Mechanism of Monomolecular Heterolysis of Commercial Organohalogen Compounds: XXXVI.1 Solvent Effect on the Activation Parameters of Heterolysis of 1-Methyl-1-chlorocyclohexane. Correlation Analysis of Solvation Effects in Heterolysis of 1-Methyl-1-chlorocyclohexane and 1-Methyl-1-chlorocyclopentane |
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| Authors: | Dvorko G F Koshchii I V Ponomareva E A |
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| Institution: | (1) Kiev Polytechnic Institute, National Technical University of the Ukraine, Kiev, Ukraine |
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| Abstract: | The kinetics of heterolysis of 1-methyl-1-chlorocyclohexane in six protic and eight aprotic solvents at 25-50°C was studied by the verdazyl method; v = kRCl], E1 mechanism. The correlation analysis of the solvent effects on the activation free energy  G
 , enthalpy H
, and entropy S
of heterolysis of 1-methyl-1-chlorocyclohexane and 1-methyl-1-chlorocyclopentane was performed for the same sets of solvents. |
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