Nucleophilic addition to acetylenes in superbasic catalytic systems: XV. Vinylation of 2-hydroxymethylfuran |
| |
| Authors: | L A Oparina O V Vysotskaya A V Stepanov I V Rodionova G F Myachina N K Gusarova B A Trofimov |
| |
| Institution: | (1) Favorskii Irkutsk Institute of Chemistry, Siberian Division, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia |
| |
| Abstract: | 2-Hydroxymethylfuran reacted with acetylene in superbasic catalytic systems MOH-DMSO (M = Na, K) under mild temperature conditions (75–85°C, 1–2 h), yielding 80% of 2-vinyloxymethylfuran. The product, as well as acetaldehyde acetals derived therefrom, turned out to be promising as modifiers for electrolyte in lithium-sulfur rechargeable batteries. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
