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离子交换树脂催化合成碳酸亚丙酯
引用本文:朱宏,陈立班,江英彦.离子交换树脂催化合成碳酸亚丙酯[J].广州化学,1996(4).
作者姓名:朱宏  陈立班  江英彦
作者单位:中国科学院广州化学研究所!广州(朱宏,陈立班),中国科学院化学研究所!北京(江英彦)
摘    要:碘型离子交换树脂在某些偶极非质子性溶剂的作用下,能有效地催化二氧化碳与环氧丙烷合成碳酸亚丙酯,并能重复使用至少10次而仍能保持较高的催化活性。

关 键 词:阴离子交换树脂  二氧化碳  环氧丙烷  碳酸亚丙酯

Synthesis of propylene carbonate catalyzed by anion exchange resins
Zhu Hong, Chen Liban.Synthesis of propylene carbonate catalyzed by anion exchange resins[J].Guangzhou Chemistry,1996(4).
Authors:Zhu Hong  Chen Liban
Abstract:The iodide form of anion exchange resins with quaternary ammonium were found to be effective for catalyzing the synthesis of propylene carbonate from carbon dioxide and propylene oxide and could be reused for many runs without much loss of catalytic activity. Futhermore, the catalytic activity of the resins could be enhanced by using properdipolar aprotic solvents, such as DMF and PC (propylene carbonate).
Keywords:anion exchange resins  carbon dioxide  propylene oxide  propylene carbonate
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