Microstructure of fiber-like SiC/Si3N4 composite particulate

The microstructure of fiber-like SiC/Si₃N₄ composite particulate was investigated using high-resolution transmission electron microscopy techniques. The SiC/Si₃N₄ composite particulate consisted of a-SiC core and a -Si₃N₄ outer shell. Two kinds of composite particulate were distinguished when the observed orientation of the SiC core was <110>. In one type of the SiC/Si₃N₄ composite particulate, a crystal relationship of (111)-SiC | (102) -Si₃N₄ and (111)-SiC (114) -Si₃N₄ was identified; in the other type of the SiC/Si₃N₄ composite particulate, a crystal relationship of (111)-SiC (001) -Si₃N₄, and (111)-SiC (101) -Si₃N₄ was observed.