New chloro- and trifluoroacetato tricarbonylrhenium(I) complexes with a N,N′-bis(benzophenone)-1,2-diiminoethane Schiff base ligand: Spectral and structural studies |
| |
| Authors: | Reza Kia Valiollah Mirkhani Alajos Kálmán Andrea Deák |
| |
| Institution: | 1. Department of Chemistry, University of Isfahan, Isfahan 81746-73441, Iran;2. Institute of Structural Chemistry, Chemical Research Center of the Hungarian Academy of Sciences, P.O. Box 17, H-1525 Budapest, Hungary |
| |
| Abstract: | The reaction of Re(CO)5Cl with the chelating ligand N,N′-bis(benzophenone)-1,2-diiminoethane (bz2en) afforded the neutral fac-Re(CO)3(bz2en)Cl]. The subsequent reaction with AgOCOCF3 gave fac-Re(CO)3(bz2en)OCOCF3]. Their pseudooctahedral fac structures have been established by FTIR, UV–Vis, 1H, 13C NMR and have been confirmed by X-ray diffraction analysis. The electrochemical behaviour of the investigated complexes has been studied by cyclic voltammetry. |
| |
| Keywords: | Rhenium(I) complexes Diimine ligand X-ray crystal structure |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
