| Ni（Ⅱ）,Cu（Ⅱ）,Zn（Ⅱ）的硝酸盐与氟哌酸的固态配合物的 … |
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| 引用本文： | 张秀利 戴玉杰. Ni（Ⅱ）,Cu（Ⅱ）,Zn（Ⅱ）的硝酸盐与氟哌酸的固态配合物的 …[J]. 光谱学与光谱分析, 2000, 20(3): 333-335 |
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| 作者姓名： | 张秀利 戴玉杰 |
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| 作者单位： | [1]中国科学院上海原子核研究所 [2]石家庄铁道学院基础部 |
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| 摘 要： | 由氟哌酸与Ｎｉ（Ⅱ）、Ｃｕ（Ⅱ）、Ｚｎ（Ⅱ）的硝酸盐合成了三个未见报道的固态配合物，并用元素分析、摩尔电导、红外光谱、热重分析表征了它们的组成和性质。
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| 关 键 词： | 氟哌酸 配合物 合成 表征 镍 铜 锌 硝酸盐 |
Synthesis and characterization of the solid complexes of Ni(II), Cu(II) and Zn(II) nitrates with norfloxacin] |
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| Xiuli ZHANG. Synthesis and characterization of the solid complexes of Ni(II), Cu(II) and Zn(II) nitrates with norfloxacin][J]. Spectroscopy and Spectral Analysis, 2000, 20(3): 333-335 |
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| Authors: | Xiuli ZHANG |
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| Affiliation: | Shanghai Institute of Nuclear Research, Chinese Academy of Sciences, 201800 Shanghai. |
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| Abstract: | Three solid complexes of Ni (II), Cu (II) and Zn (II) nitrates with norfloxacin, having the composition of [Ni (NFA)2 (NO3)] NO3.2H2O, [Ca (NFA)2] (NO3)2.H2O, [Zn (NFA)2 (NO3)] NO3.2H2O, have been synthesized in aqueous solvent. All the isolated complexes have been characterized by elemental analysis, IR spectra, thermogravimetric analysis and molar conductance in methanol. The results show that [Ni (Ni (NFA)2) (NO3)] NO3.2H2O, [Zn (NFA)2 (NO3)] NO3.2H2O are 1:1 tape electrolytes in methanol, their coordination numbers are all 6. The nitrates of inner boundary are all bidenlate ligands. The complex torming with copper nitrate and norfloxacin is non-electrolyte in methanol, the coordination number is 4. Norfloxacin molecules with inner salt types are all bidenlate ligands. |
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| Keywords: | Norfloxacin Complexes Transition metals |
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