| 半夹芯16电子碳硼烷化合物Me4CpCoS2C2B10H10与二茂铁炔酮的反应性 |
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| 引用本文： | 叶红德,幸泽升,胡久荣,彭化南,谢嘉霖,刘林海.半夹芯16电子碳硼烷化合物Me4CpCoS2C2B10H10与二茂铁炔酮的反应性[J].无机化学学报,2015,31(8):1534-1538. |
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| 作者姓名： | 叶红德 幸泽升 胡久荣 彭化南 谢嘉霖 刘林海 |
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| 作者单位： | 上饶师范学院化学化工学院, 江西省普通高校应用有机化学重点实验室, 上饶 334001;南京大学化学化工学院, 配位化学国家重点实验室, 南京 210093,上饶师范学院化学化工学院, 江西省普通高校应用有机化学重点实验室, 上饶 334001,上饶师范学院化学化工学院, 江西省普通高校应用有机化学重点实验室, 上饶 334001,上饶师范学院化学化工学院, 江西省普通高校应用有机化学重点实验室, 上饶 334001,上饶师范学院化学化工学院, 江西省普通高校应用有机化学重点实验室, 上饶 334001,上饶师范学院化学化工学院, 江西省普通高校应用有机化学重点实验室, 上饶 334001 |
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| 基金项目： | 国家自然科学基金(No.21361022、21261020),江西省教育厅2014年度普通本科高校大学生创新创业教育计划项目,南京大学配位化学 国家重点实验室第25批开发课题,第54批中国博士后科学基金面上基金(No.2013M541640)资助项目。 |
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| 摘 要： | 邻位碳硼烷分别与正丁基锂、硫粉和Me4CpCo(CO)I2反应合成得到半夹芯16电子碳硼烷化合物Me4CpCoS2C2B10H10 (1)。1与二茂铁炔酮在二氯甲烷中反应得到产物{(Me4CpCoS2C2B10H10)FcC(O)CHCCHCC(O)Fc]} (2)(Fc=二茂铁基)。2是一个1:2的加成产物,2个二茂铁炔酮分子以头-尾的方式加成到分子1中的1个Co-S键上。1和2分别用红外、核磁、元素分析、质谱和单晶X-射线衍射等表征方法进行了结构表征。
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| 关 键 词： | 半夹芯 碳硼烷 二茂铁炔酮 表征 |
| 收稿时间： | 2015/1/28 0:00:00 |
| 修稿时间： | 2015/3/20 0:00:00 |
Reactivity of Half-Sandwich 16e Carborane Compound Me4CpCoS2C2B10H10 with Ferrocenyne Ketone |
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| YE Hong-De,XING Ze-Sheng,HU Jiu-Rong,PENG Hua-Nan,XIE Jia-Lin and LIU Lin-Hai.Reactivity of Half-Sandwich 16e Carborane Compound Me4CpCoS2C2B10H10 with Ferrocenyne Ketone[J].Chinese Journal of Inorganic Chemistry,2015,31(8):1534-1538. |
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| Authors: | YE Hong-De XING Ze-Sheng HU Jiu-Rong PENG Hua-Nan XIE Jia-Lin and LIU Lin-Hai |
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| Institution: | Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, School of Chemistry and Chemical Engineering, Shangrao Normal University, Shangrao, Jiangxi 334001, China;State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China,Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, School of Chemistry and Chemical Engineering, Shangrao Normal University, Shangrao, Jiangxi 334001, China,Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, School of Chemistry and Chemical Engineering, Shangrao Normal University, Shangrao, Jiangxi 334001, China,Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, School of Chemistry and Chemical Engineering, Shangrao Normal University, Shangrao, Jiangxi 334001, China,Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, School of Chemistry and Chemical Engineering, Shangrao Normal University, Shangrao, Jiangxi 334001, China and Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, School of Chemistry and Chemical Engineering, Shangrao Normal University, Shangrao, Jiangxi 334001, China |
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| Abstract: | o-Carborane reacts with n-butyllithium, sulfur powder and Me4CpCo(CO)I2 respectively to give the half-sandwich 16e carborane compound Me4CpCoS2C2B10H10 (1). The reaction of 1 with ferrocenyne ketone in dichloro-methane leads to the product {(Me4CpCoS2C2B10H10)FcC(O)CHCCHCC(O)Fc]} (2) (Fc=ferrocenyl). 2 is a 1:2 adduct. The alkynone is twofold inserted into one Co-S bond of 2 in a head-tail mode. 1 and 2 have been characterized by IR, NMR, elemental analysis, mass spectrum and single-crystal X-ray diffraction analysis. CCDC: 1045890, 1; 1045891, 2. |
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| Keywords: | half-sandwich carborane ferrocenyne ketone characterization |
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