Hydrothermal and Solvothermal Synthesis of the Complex Fluoride α′-SrAlF_5 |
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引用本文: | 贾志宏,华瑞年,石春山.Hydrothermal and Solvothermal Synthesis of the Complex Fluoride α′-SrAlF_5[J].中国化学,2003(8). |
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作者姓名: | 贾志宏 华瑞年 石春山 |
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作者单位: | Key Laboratory of Rare Earth Chemistry and Physics,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Faculty of Chemistry,Northeast Normal University,Changchun,Key Laboratory of Rare Earth Chemistry and Physics,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences Changchun,Jilin 130022,China,Jilin130024,China,Changchun,Jilin 130022,China |
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基金项目: | theMajorStateBasicResearchDevelopmentProgram (No .G19980 613 0 6) |
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摘 要: | Introduction Strontiumaluminumpentafluoride SrAlF5isagoodhostforthespectralresearchofdopedrareearthionsduetoitsweakcrystalfieldenvironment.Forthefirsttime ,Hewesetal.1foundthef→flineemissionoftheEu2 + inSrAlF5matrix ,andfournonequivalentsitesforRE2 + inSrAlF5havealsobeenreported .2 Theobservationofthetunable laserofCr3+ from 85 2to 94 7nminSrAlF5hasat tractedconsiderableattention3andtheferroelectricbehav ior4 ofSrAlF5hasextendeditsapplicablefield .Twogener almethods,high temperatur…
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