Rh(II)-catalyzed formation and rearrangement of trifluoroacetyl-containing sulfur ylides |
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| Authors: | Wan Pang Shifa Zhu Shizheng Zhu |
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| Institution: | a College of Chemistry, South China University of Technology, Guangzhou 510640, China
b Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, China |
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| Abstract: | A facile, convenient, efficient, and high yielding Rh(II)-catalyzed formation and rearrangement of trifluoroacetyl-containing sulfur ylides are reported. It is a Rh2(OAc)4-catalyzed 2,3]-sigmatropic rearrangement of sulfur ylide intermediates generated from α-diazo compounds. |
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| Keywords: | Rh(II)-catalyst Fluorinated diazo compounds Sulfur ylide Rearrangement |
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