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Total synthesis of natural products using a desymmetrization strategy |
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| Authors: | Makoto Inai Tomohiro Asakawa Toshiyuki Kan | |
| Affiliation: | 1. School of Pharmaceutical Sciences, University of Shizuoka, 52-1 Yada, Suruga-ku, Shizuoka 422-8526, Japan;2. Institute of Innovative Science and Technology, Tokai University, 4-1-1, Kitakaname, Hiratsuka-city, Kanagawa 259-1292, Japan | |
| Abstract: | Total syntheses of SB-203207 (1) and sphingofungin E (2) were accomplished by utilizing an asymmetric desymmetrization strategy to introduce multiple stereogenic centers into meso starting compounds in a single step. Thus, rhodium carbenoid-mediated C | |
| Keywords: | Total synthesis Desymmetrization SB-203207 Sphingofungin E Pactamycin | |
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