An extension of nickel-catalyzed reductive coupling between tertiary alkyl halides with allylic carbonates |
| |
| Authors: | Yingying Yu Haifeng Chen Qun Qian Ken Yao Hegui Gong |
| |
| Affiliation: | 1. Department of Chemistry, Shanghai University, 99 Shang-Da Road, Shanghai 200444, China;2. School of Materials Science and Engineering, Shanghai University, China |
| |
| Abstract: | The nickel catalyzed reductive coupling of allylic carbonates with chloro-cyclotryptamine analogs to construct sterically congested all C(sp3) quaternary centers has been achieved with emphasis on the substrate scope. And the using of dienyl methyleneyl carbonates coupling with a variety of tertiary alkyl halides furnished the dienylated products improved the reaction's applicability. |
| |
| Keywords: | Allylation Chloro-cyclotryptamine Nickel catalyzed Extension Dienyl carbonate |
| 本文献已被 ScienceDirect 等数据库收录！ |
