Radiohochspannungsionophoretische Untersuchungen der Isotopenaustauschreaktionen zwischen Polythionaten,Thiosulfat und Sulfit |
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Authors: | H. Wagner H. Schreier |
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Affiliation: | 1. Fachrichtung Anorganische Analytik und Radiochemie der Universit?t des Saarlandes, 6600, Saarbrücken, BRD
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Abstract: | The isotopic exchange of35S between thiosulfate/sulfite and tetrathionate/thiosulfate is examined. The kinetic data are determined. In both cases the reactions are of second order. As the isotopic exchange between tetrathionate/thiosulfate is very fast, these reaction components are used in high dilution. Furthermore, the extent of exchange during the separation is determined. |
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